Total organofluorine (TOF) testing for PFAS
The screening method for PFAS — what it measures, what it doesn't, and when to follow up with targeted testing.
PFAS regulations don't usually name specific chemicals to test — they focus on 'intentionally added' PFAS as a class. TOF (total organofluorine) is the screening method most labs use to detect PFAS as a whole, then targeted testing identifies which specific compounds are present when the screen flags positive.
What TOF measures:
- Total fluorine bound to carbon atoms across the PFAS class
- Reported in parts per million (ppm) or μg/g
- Catches the ~12,000 PFAS variants without needing to test each one individually
What TOF doesn't tell you:
- Which specific PFAS are present (PFOA vs PFOS vs GenX vs PTFE)
- Whether the PFAS was intentionally added or incidental contamination
- Whether the level meets a particular state's threshold
When to follow up with targeted testing:
- TOF result is above 50 ppm (most state thresholds use a 100 ppm intentional-addition limit)
- Maine LD 1503 disclosure requires you to identify intentionally-added PFAS by name
- A regulator requests it during enforcement
Targeted methods: EPA 537.1, EPA 533, ASTM D7979, or LC-MS/MS panels covering 30–60 specific PFAS.
TIP: Cost: TOF screening runs $200–$400 per SKU; targeted PFAS panels run $500–$1,200. Lead time: 7–14 business days for TOF, 14–21 for targeted. Plan for both if you sell into Maine.
WARNING: PTFE-coated cookware can show high TOF readings even though PTFE itself is not classed as restricted in most state laws. Targeted testing is what proves the difference.